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Life cycle assessment and economic analysis of HFC-134a production from natural gas compared with oil-basedand coal-based production

《化学科学与工程前沿（英文）》 2022年第16卷第12期页码 1713-1725 doi: 10.1007/s11705-022-2210-y

摘要： China is the largest producer and consumer of HFC-134a (1,1,1,2-tetrafluoroethane) in the world. Coal-based route is mainly adopted to produce HFC-134a, which suffers from large waste and CO₂ emissions. Natural gas is a low-carbon and clean energy resource, and no research has been found on the environment and economy of producing HFC-134a from natural gas. In this study, CML 2001 method was used to carry out the life cycle assessment of natural gas (partial oxidation)-based and natural gas (plasma cracking)-based routes (abbreviated as gas(O)-based and gas(P)-based routes, respectively), and their environmental performances were compared with coal-based and oil-based routes. Meanwhile, considering that China is vigorously promoting the transformation of energy structure, and the application of electric heating equipment to replace fossil-based heating equipment in industrial field, which has a great impact on the environmental performance of the production processes, the authors conducted a scenario analysis. The results showed that the gas(O)-based route had the most favourable environmental benefits. However, the gas(P)-based route had the highest potential for reducing environmental burdens, and its environmental benefit was the most favourable in scenario 2050. Additionally, the economic performance of the gas(P)-based route was significantly better than that of gas(O)-based and coal-based routes.

关键词： life cycle assessment economic performance HFC-134a natural gas oil coal

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Computational design of structured chemical products

Faheem Mushtaq, Xiang Zhang, Ka Y. Fung, Ka M. Ng

《化学科学与工程前沿（英文）》 2021年第15卷第5期页码 1033-1049 doi: 10.1007/s11705-020-2002-1

摘要： In chemical product design, the aim is to formulate a product with desired performance. Ingredients and internal product structure are two key drivers of product performance with direct impact on the mechanical, electrical, and thermal properties. Thus, there is a keen interest in elucidating the dependence of product performance on ingredients, structure, and the manufacturing process to form the structure. Design of product structure, particularly microstructure, is an intrinsically complex problem that involves different phases of different physicochemical properties, mass fraction, morphology, size distribution, and interconnectivity. Recently, computational methods have emerged that assist systematic microstructure quantification and prediction. The objective of this paper is to review these computational methods and to show how these methods as well as other developments in product design can work seamlessly in a proposed performance, ingredients, structure, and manufacturing process framework for the design of structured chemical products. It begins with the desired target properties and key ingredients. This is followed by computation for microstructure and then selection of processing steps to realize this microstructure. The framework is illustrated with the design of nanodielectric and die attach adhesive products.

关键词： product design performance ingredients structure manufacturing process framework structured chemical products microstructure design

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Biodiesel production by the transesterification of cottonseed oil by solid acid catalysts

CHEN He, PENG Baoxiang, WANG Dezheng, WANG Jinfu

《化学科学与工程前沿（英文）》 2007年第1卷第1期页码 11-15 doi: 10.1007/s11705-007-0003-y

摘要： Methyl esters (biodiesel) were produced by the transesterification of cottonseed oil with methanol in the presence of solid acids as heterogeneous catalysts. The solid acids were prepared by mounting HSO on TiO · nHO and Zr(OH), respectively, followed by calcining at 823K. TiO-SO and ZrOSO showed high activity for the transesterification. The yield of methyl esters was over 90% under the conditions of 230°C, methanol/oil mole ratio of 12:1, reaction time 8 h and catalyst amount (catalyst/oil) of 2% (w). The solid acid catalysts showed more better adaptability than solid base catalysts when the oil has high acidity. IR spectral analysis of absorbed pyridine on the samples showed that there were Lewis and BrØnsted acid sites on the catalysts.

关键词： BrØnsted reaction presence cottonseed biodiesel

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Environmental and economic assessment of vegetable oil production using membrane separation and vapor

Weibin Kong, Qi Miao, Peiyong Qin, Jan Baeyens, Tianwei Tan

《化学科学与工程前沿（英文）》 2017年第11卷第2期页码 166-176 doi: 10.1007/s11705-017-1616-4

摘要： Solvent extraction of crude oil from oilseeds is widely applied for its high production capacity and low cost. In this process, solvent recovery and tail gas treatment are usually performed by adsorption, paraffin scrubbing, or even cryogenics (at low tail gas flow rates). Membrane separation, which has a lower energy consumption than these techniques, spans a broad range of admissible concentrations and flow rates, and is moreover easily combined with other techniques. Vapor recompression has potentials to reduce the heat loss in association with distillation and evaporation. In this study, we proved the possibility of combining membrane separation and vapor recompression to improve the conventional vegetable oil production, by both experiments and process simulation. Nearly 73% of energy can be saved in the process of vegetable oil extraction by the novel processing approach. By further environmental assessment, several impact categories show that the optimized process is environmentally sustainable.

关键词： vegetable oil solvent-extraction membrane separation vapor recompression environmental and economic assessment

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Potential hybrid feedstock for biodiesel production in the tropics

Solomon GIWA,Oludaisi ADEKOMAYA,Collins NWAOKOCHA

《能源前沿（英文）》 2016年第10卷第3期页码 329-336 doi: 10.1007/s11708-016-0408-8

摘要： Recently, mixture of different oils at various proportions have been used as feedstock for biodiesel production. The primary aim is to improve fuel properties which are strongly influenced by the fatty acid composition of the individual oil that makes up the feedstock mix. The tropics are renowned for abundant oil-bearing crops of which palm kernel oil (PKO) from palm seed and groundnut oil (GNO) are prominent. This present paper investigated biodiesel production from hybrid oil (HO) of PKO (medium carbon chain and highly saturated oil) and GNO (long carbon chain and highly unsaturated oil) at 50/50 (v/v) blending. The principal fatty acids (FAs) in the HO are oleic (35.62%) and lauric acids (24.23%) with 47.80% of saturated FA and 52.26% of unsaturated FA contents. The chemical conversion of the oil to methyl ester (ME) gave 86.56% yield. Fuel properties of hybrid oil methyl ester (the HOME) were determined in accordance with standard test methods and were found to comply with both ASTM D6751 and EN 14214 standards. The oxidative stability, cetane number and kinematic viscosity (KV) of HOME were observed to be improved when compared with those of GNO methyl ester from single parent oil, which could be accredited to the improved FA composition of the HO. The KV (3.69 mm /s) of HOME obtained in this paper was remarkably low compared with those reported in literature for most biodiesels. This value suggests better flow, atomization, spray and combustion of this fuel. Conclusively, the binary blend of oils can be a viable option to improve the fuel properties of biodiesel feedstock coupled with reduced cost.

关键词： groundnut oil palm kernel oil methyl ester fuel properties tropics fatty acid composition

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Biodiesel production from waste frying oil in sub- and supercritical methanol on a zeolite Y solid acid

Jorge MEDINA-VALTIERRA, Jorge RAMIREZ-ORTIZ

《化学科学与工程前沿（英文）》 2013年第7卷第4期页码 401-407 doi: 10.1007/s11705-013-1354-1

摘要： Waste frying oil (WFO) is a very important feedstock for obtaining biodiesel at low cost and using WFO in transesterification reactions to produce biodiesel helps eliminate local environmental problems. In this study biodiesel was produced from WFO in sub- and super-critical methanol on a zeolite Y solid acid catalyst. The procedure was optimized using a design of experiments by varying the methanol to WFO molar ratio, the reaction temperature, and the amount of catalyst. Typical biodiesel yields varied from 83 to nearly 100% with methyl esters content ranging from 1.41–1.66 mol·L and typical dynamic viscosities of 22.1-8.2 cP. Gas chromatography was used to determine the molecular composition of the biodiesel. The reaction products contained over 82 wt-% methyl esters, 4.2 wt-% free acids, 13.5 wt-% monoglycerides, and 0.3 wt-% diglycerides. The transesterification of WFO with methanol around its critical temperature combined with a zeolite Y as an acid catalyst is an efficient approach for the production of biodiesel with acceptable yields.

关键词： biodiesel methanol critical temperature waste frying oil zeolite Y

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用哲学的思维提升采油工程技术管理水平

刘合

《中国工程科学》 2013年第15卷第11期页码 31-35

摘要：

在中国石油工业的发展历史过程中，始终用哲学的思维指导我们的工作，特别是大庆油田是靠毛泽东的哲学思想，即《矛盾论》、《实践论》起家的，依靠哲学的思维在科学的发展中不断完善管理和技术创新体系，形成了具有大庆特色专业技术的管理系统。本文就采油工程系统应用“两论”的思想，认真分析影响4.0×107 t稳产的主要矛盾和对策，用实践的科学方法论，指导攻关的技术思路和措施，为大庆油田4.0×107 t 稳产不断发挥了保障作用。

关键词：哲学矛盾实践采油工程

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Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2019年第13卷第4期页码 702-717 doi: 10.1007/s11705-019-1861-9

摘要： The work studied a non-catalytic upgrading of fast pyrolysis bio-oil by blending under supercritical conditions using methanol, ethanol and isopropanol as solvent and hydrogen donor. Characterisation of the bio-oil and the upgraded bio-oils was carried out including moisture content, elemental content, pH, heating value, gas chromatography-mass spectrometry (GCMS), Fourier transform infrared radiation, C nuclear magnetic resonance spectroscopy, and thermogravimetric analysis to evaluate the effects of blending and supercritical reactions. The GCMS analysis indicated that the supercritical methanol reaction removed the acids in the bio-oil consequently the pH increased from 2.39 in the crude bio-oil to 4.04 after the supercritical methanol reaction. The ester contents increased by 87.49% after the supercritical methanol reaction indicating ester formation could be the major deacidification mechanism for reducing the acidity of the bio-oil and improving its pH value. Simply blending crude bio-oil with isopropanol was effective in increasing the C and H content, reducing the O content and increasing the heating value to 27.55 from 17.51 MJ·kg in the crude bio-oil. After the supercritical isopropanol reaction, the heating value of the liquid product slightly further increased to 28.85 MJ·kg .

关键词： bio-oil blending supercritical upgrading characterisation

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Lessons learned from developing and implementing refinery production scheduling technologies

Marcel JOLY, Mario Y. MIYAKE

《工程管理前沿（英文）》 2017年第4卷第3期页码 325-337 doi: 10.15302/J-FEM-2017033

摘要： An increasing number of novel and highly specialized computer-aided decision-making technologies for short-term production scheduling in oil refineries has emerged and evolved over the past two decades, thereby encouraging refiners to permanently rethink the way the refining business is operated and managed. In this report, we discuss the key lessons learned from one of the pioneering, yet daring, enterprise-wide programs entirely implemented in an energy company devoted to developing and implementing an advanced refinery production scheduling (RPS) technology, i.e., the RPS system of Petrobras. Apart from mathematical and information technology issues, the long-term sustainability of a successful RPS project is, we argue, the outcome of a virtuous cycle grounded on permanent actions devoted to improving technical education inside the organization, reinspecting organizational cultures and operational paradigms, and developing working processes.

关键词： automation decision making oil refinery optimization production scheduling

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解决城市中的全球重大挑战 Views & Comments

Andrew Ka-Ching Chan, FREng

《工程（英文）》 2016年第2卷第1期页码 10-15 doi: 10.1016/J.ENG.2016.01.003

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Metakaolinite as a catalyst for biodiesel production from waste cooking oil

Jorge RAMIREZ-ORTIZ, Merced MARTINEZ, Horacio FLORES

《化学科学与工程前沿（英文）》 2012年第6卷第4期页码 403-409 doi: 10.1007/s11705-012-1224-2

摘要： The use of metakaolinite as a catalyst in the transesterification reaction of waste cooking oil with methanol to obtain fatty acid methyl esters (biodiesel) was studied. Kaolinite was thermally activated by dehydroxylation to obtain the metakaolinite phase. Metakaolinite samples were characterized using X-ray diffraction, N adsorption-desorption, simultaneous thermo-gravimetric analyse/differential scanning calorimetry (TGA/DSC) experiments on the thermal decomposition of kaolinite and Fourier-transform infrared spectrometer (FTIR) analysis. Parameters related to the transesterification reaction, including temperature, time, the amount of catalyst and the molar ratio of waste cooking oil to methanol, were also investigated. The transesterification reaction produced biodiesel in a maximum yield of 95% under the following conditions: metakaolinite, 5 wt-% (relative to oil); molar ratio of oil to methanol, 1∶23; reaction temperature, 160°C; reaction time, 4 h. After eight consecutive reaction cycles, the metakaolinite can be recovered and reused after being washed and dried. The biodiesel thus obtained exhibited a viscosity of 5.4?mm ?s and a density of 900.1 kg?m . The results showed that metakaolinite is a prominent, inexpensive, reusable and thermally stable catalyst for the transesterification of waste cooking oil.

关键词： biodiesel metakaolinite transesterification waste cooking oil

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Numerical investigation on side heat transfer enhancement in 300 kA aluminum reduction cell

WANG Changhong, ZHU Dongsheng, LEI Junxi, ZHOU Jiemin

《能源前沿（英文）》 2008年第2卷第3期页码 256-260 doi: 10.1007/s11708-008-0051-0

摘要： Industrial test and numerical simulation were synchronously applied to analyze the side heat transfer process and enhance heat transfer in aluminum reduction cell. The 3D slice finite element model of aluminum reduction cell was developed, with which the sidewall temperature field of the cell was computed by using software ANSYS. The main influencing factors on heat dissipation were analyzed and some effective measures were proposed to enhance sidewall heat transfer. The results show that the shell temperature of the test cell and the common cell is respectively 312°C and 318°C and the ledge thickness is 16 cm and 15 cm when side coefficient of heat transfer between the shell and the surroundings is 70 W/(mK). With the increase of the side coefficient of heat transfer between the shell and the surroundings, the temperature of the shell decreases but the thickness of the side ledge increases when the electrolytic temperature, the ambient temperature, the coefficient of heat transfer between molten bath and ledge, the eutectic temperature and the thermo-resistance of the side lining are constant.

关键词： constant ambient temperature thickness electrolytic temperature transfer process

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中国食用油安全战略转变：国内条件与国际情景

马文杰

《中国工程科学》 2016年第18卷第1期页码 42-47 doi: 10.15302/J-SSCAE-2016.01.006

摘要：

食用油料成为我国对国际市场依存度最大的大宗农产品，是造成农产品国际贸易逆差的主要成因。国产植物油料的大量进口对国家粮食与食物安全、居民消费甚至国民经济均产生较为重要的影响。在新的粮食安全战略下，我国食用油作物面积增长空间有限、兼用油源生产潜力巨大，但转化为现实产量困难重重，未来消费量将进一步增加。在国产植物油料大量进口新常态下，世界食用油生产潜力巨大、我国具有从世界市场稳定获取食用油料的能力、食用油料供给安全外部环境复杂。针对新的国内条件与国际情景，论文给出我国新的食用油安全战略：维持能力、保留基准、积极进口、健康消费。

关键词：食用油国内条件国际情景生产潜力战略转变

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水下生产系统在我国南海深水油气田开发的应用与挑战

刘太元,霍成索,李清平,万祥,李文英

《中国工程科学》 2015年第17卷第1期页码 51-55

摘要：

随着各大石油公司对深水油气资源勘探开发投入的不断增加，水下生产系统得到越来越多的应用。水下生产系统灵活性强，可以适应不同的油气田开发方案。在总结分析目前水下生产系统相关技术现状的基础上，指出了未来水下生产系统发展的方向，同时结合我国南海特有的海况和地质条件及深水油气田开发现状，给出了水下生产系统在应用中的困难与挑战及相应的应对措施，对于未来水下生产系统的应用有一定的参考意义。

关键词：深水；水下生产系统；油气田开发；南海开发；应用与挑战

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海上采油工艺新技术与实践综述

徐文江,丘宗杰,张凤久

《中国工程科学》 2011年第13卷第5期页码 53-57

摘要：

结合“十一五”期间海上油田开发生产所面临的挑战，介绍了采油工艺方面探索和取得的新成果。

关键词：采油工艺实践技术综述